Jundishapur Journal of Health Sciences

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Effects of pH on the Kinetics of Methyl Tertiary Butyl Ether Degradation by Oxidation Process (H2O2/Nano Zero-Valent Iron/Ultrasonic)

Mohammad Reza Samaei 1 , * , Hoshang Maleknia 1 and Abooalfazl Azhdarpoor 1
Authors Information
1 Department of Environmental Health Engineering, School of Health, Shiraz University of Medical Sciences, Shiraz, IR Iran
Article information
  • Jundishapur Journal of Health Sciences: July 01, 2015, 7 (3); e30285
  • Published Online: July 25, 2015
  • Article Type: Research Article
  • Received: May 26, 2015
  • Revised: June 20, 2015
  • Accepted: June 27, 2015
  • DOI: 10.17795/jjhs-30285

To Cite: Samaei M R, Maleknia H, Azhdarpoor A. Effects of pH on the Kinetics of Methyl Tertiary Butyl Ether Degradation by Oxidation Process (H2O2/Nano Zero-Valent Iron/Ultrasonic), Jundishapur J Health Sci. 2015 ; 7(3):e30285. doi: 10.17795/jjhs-30285.

Copyright © 2015, Ahvaz Jundishapur University of Medical Sciences. This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International License (http://creativecommons.org/licenses/by-nc/4.0/) which permits copy and redistribute the material just in noncommercial usages, provided the original work is properly cited.
1. Background
2. Objectives
3. Materials and Methods
4. Results
5. Discussion
  • 1. Bremner DH, Molina R, Martínez F, Melero JA, Segura Y. Degradation of phenolic aqueous solutions by high frequency sono-Fenton systems (US–Fe2O3/SBA-15–H2O2). Appl Catalysis B Environ. 2009; 90(3-4): 380-8[DOI]
  • 2. Azizi E, Ghayebzadeh M, Beikmohammadi M, Sharafi K, Pirsaheb M. Oxidation of aniline with photo-Fenton advanced oxidation process from aqueous solutions in batch reactor. Tech J Engin Applied Sci. 2015; 5(2): 12-6
  • 3. Xu L, Wang J. A heterogeneous Fenton-like system with nanoparticulate zero-valent iron for removal of 4-chloro-3-methyl phenol. J Hazard Mater. 2011; 186(1): 256-64[DOI][PubMed]
  • 4. Xu XR, Zhao ZY, Li XY, Gu JD. Chemical oxidative degradation of methyl tert-butyl ether in aqueous solution by Fenton's reagent. Chemosphere. 2004; 55(1): 73-9[DOI][PubMed]
  • 5. Zhou H, Shen Y, Lv P, Wang J, Li P. Degradation pathway and kinetics of 1-alkyl-3-methylimidazolium bromides oxidation in an ultrasonic nanoscale zero-valent iron/hydrogen peroxide system. J Hazard Mater. 2015; 284: 241-52[DOI][PubMed]
  • 6. Burbano AA, Dionysiou DD, Suidan MT, Richardson TL. Oxidation kinetics and effect of pH on the degradation of MTBE with Fenton reagent. Water Res. 2005; 39(1): 107-18[DOI][PubMed]
  • 7. Zha S, Cheng Y, Gao Y, Chen Z, Megharaj M, Naidu R. Nanoscale zero-valent iron as a catalyst for heterogeneous Fenton oxidation of amoxicillin. Chem Engin J. 2014; 255: 141-8[DOI]
  • 8. Rahmani AR, Ghafari HR,, Samadi MT, Zarabi M. Synthesis of Zero Valent Iron Nanoparticles (NZVI) and its Efficiency in Arsenic Removal from Aqueous Solutions. Water Wastewater. 2011; 1: 35-41
  • 9. Eglal MM. Nanofer Zero-Valent Iron Nanoparticles: Surface Morphology, Structure and Reactivity with Contaminants, in Department of Building, Civil and Environmental Engineering, Concordia University. 2014;
  • 10. Janda V, Vasek P, Bizova J, Belohlav Z. Kinetic models for volatile chlorinated hydrocarbons removal by zero-valent iron. Chemosphere. 2004; 54(7): 917-25[DOI][PubMed]
  • 11. the use of ultrasound technology in wastewater treatment. the Sixth National Conference of Environmental Engineering.
  • 12. Chen D. Handbook on application of ultrasound, sonochemistry for sustainability. 2012;
  • 13. Taha MR, Ibrahim AH. Characterization of nano zero-valent iron (nZVI) and its application in sono-Fenton process to remove COD in palm oil mill effluent. J Environ Chem Engin. 2014; 2(1): 1-8[DOI]
  • 14. Rosenfeldt EJ, Linden KG. Degradation of endocrine disrupting chemicals bisphenol A, ethinyl estradiol, and estradiol during UV photolysis and advanced oxidation processes. Environ Sci Technol. 2004; 38(20): 5476-83
  • 15. Sun JH, Sun SP, Fan MH, Guo HQ, Qiao LP, Sun RX. A kinetic study on the degradation of p-nitroaniline by Fenton oxidation process. J Hazard Mater. 2007; 148(1-2): 172-7[DOI][PubMed]
  • 16. Boonrattanakij N, Lu MC, Anotai J. Kinetics and mechanism of 2,6-dimethyl-aniline degradation by hydroxyl radicals. J Hazard Mater. 2009; 172(2-3): 952-7[DOI][PubMed]
  • 17. Hwang S, Huling SG, Ko S. Fenton-like degradation of MTBE: Effects of iron counter anion and radical scavengers. Chemosphere. 2010; 78(5): 563-8[DOI][PubMed]
  • 18. Yuvakkumar R, Elango V, Rajendrana V, Kannan N. Preparation and characterization of zero valent iron Nanoparticles. Digest J Nanomaterials Biostructures. 2011; 6(4): 1771-6
  • 19. Safarzadeh-Amiri A, Bolton JR, Cater SR. The use of iron in advanced oxidation processes. J Adv Oxid Technol. 1996; 1: 18–26
  • 20. Moon BH, Park YB, Park KH. Fenton oxidation of Orange II by pre-reduction using nanoscale zero-valent iron. Desalination. 2011; 268(1-3): 249-52[DOI]
  • 21. Eslami A, Nasseri S, Yadollahi B, Mesdaghinia A, Vaezi F, Nabizadeh R. Removal of methyl tert-butyl ether (MTBE) from contaminated water by photocatalytic process. Iran Jof Public Health. 2009; 38(2): 18-26
  • 22. Darban AK, Shahmansouri A, Ganjidost H. Fenton remediation of methyl tertiary butyl ether (MTBE) and effects of reaction conditions on the byproducts formed. Water Wastewater. 2009; 56: 43-50
  • 23. Bergendahl JA, Thies TP. Fenton's oxidation of MTBE with zero-valent iron. Water Res. 2004; 38(2): 327-34[DOI][PubMed]
  • 24. Kusic H, Loncaric Bozic A, Koprivanac N. Fenton type processes for minimization of organic content in coloured wastewaters: Part I: Processes optimization. Dyes Pigments. 2007; 74(2): 380-7[DOI]
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